TY - JOUR AU - Lee, Kyuchul AU - Hwang, Jihyun AU - Park, Jeong Ho AU - Park, Jongwook AU - Lee, Kangwon AU - Ko, Jang Myoun PY - 2023 DA - 2023/02/01 TI - New quinone-based electrode additives electrochemically polymerized on activated carbon electrodes for improved pseudocapacitance JO - Macromolecular Research SP - 171 EP - 179 VL - 31 IS - 2 AB - Three quinone-based derivatives (HBU680, HBU888, and HBU889) are synthesized and separately mixed with activated carbon (AC) and electropolymerized to form a homogeneous composite electrode. The electrochemical properties of the composite electrodes are studied. The electrochemical properties are mainly characterized by PhQ-PhQH2 and Q-QH2 redox transitions. The composite electrodes show specific capacitance of 176 F/g, 262 F/g, and 145 F/g for HBU680, HBU888, and HBU889, respectively. The HBU888 shows the highest specific capacitance due to the fast PhQ-PhQH2 redox transition at a scan rate of 100 mV/s. The composite electrodes also show a 100% capacity retention over 10,000 cycles. These results show that the new quinone-based derivates can enhance pseudocapacitive behavior and warrant their use as electrode additives for supercapacitors. SN - 2092-7673 UR - https://doi.org/10.1007/s13233-023-00129-6 DO - 10.1007/s13233-023-00129-6 ID - Lee2023 ER -